For a cylinder containing dangerous goods, the label must be displayed on or near the shoulder of the cylinder as shown below [Subsection 4.10(3)]. Depending on the classification for a dangerous good, one or more of the following safety marks may be required on a large means of containment: NOTE: Generally speaking, a placard must be displayed for each of the dangerous goods transported in a large means of containment regardless of the quantity. If a mixture or solution is composed of a single predominant substance mentioned in the Dangerous Goods List and one or more substances not subject to DG classification, the mixture shall be assigned to the Proper Shipping Name of the predominant substance mentioned in the Dangerous Goods List by adding the qualifying words "MIXTURE" or "SOLUTION" unless: Example: UN 1090 ACETONE SOLUTION, or UN 1090 ACETONE 75% SOLUTION. The following packing group always takes precedence irrespective of hazards: The following hazard class always takes precedence irrespective of packing groups: If above two rules do not apply, please refer to the following hazard precedence table to choose primary hazard. Always consult the legislation that applies in your situation. (v) the subsidiary class or classes, in parentheses, which may be shown as a number only or under the heading subsidiary class or classe subsidiaire or following the words subsidiary class or classe subsidiaire, except that, for transport by aircraft or by ship, the subsidiary class or classes may be shown after the information required by this paragraph, (vi) the packing group roman numeral, which may be shown under the heading PG or GE or following the letters PG or GE or following the words Packing Group or Groupe d'emballage, and. Packing Group This column gives the packing groups of the dangerous goods. (viii) For authorized consumer commodities, the information provided may be either the gross mass of each package or the average gross mass of the packages. For example, UN2744, Cyclobutyl chloroformate, 6.1, (8, 3), PG II. Shipping descriptions for hazardous materials offered or intended for transportation by rail that contain all the information required in this subpart and that are formatted and ordered in accordance with recognized electronic data interchange standards and, to the extent possible, in the order and manner required by this subpart are deemed to comply with this paragraph. Wastes: If the product is a waste, then the shipping name is either preceded or followed by the word waste. Although every effort is made to ensure the accuracy, currency and completeness of the information, CCOHS does not guarantee, warrant, represent or undertake that the information provided is correct, accurate or current. MERCURY - UMD Mercury General It would be shipped as "UN 2809, MERCURY, 8(6.1)" and assigned to Packing Group II. Mercury Marine We do not provide consultancy services. It is determined according to the specification in section 2.8 and the Precedence of Classes Table which is provided in Part 2. 2. As per subsection 11.1(1) of the TDG Regulations, the IMDG Code must be consulted for international transport by ship. Phosphorus sesquisulphide, free from yellow and white phosphorus, Rubber scrap or Rubber shoddy, powdered or granulated, not greater than 840 mm and rubber content greater than 45%. See Section 2.4. Definition for a mixture a product that contains two or more ingredients. Electronic Code of Federal Regulations (e-CFR), Subtitle B - Other Regulations Relating to Transportation, CHAPTER I - PIPELINE AND HAZARDOUS MATERIALS SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION, SUBCHAPTER C - HAZARDOUS MATERIALS REGULATIONS, PART 172 - HAZARDOUS MATERIALS TABLE, SPECIAL PROVISIONS, HAZARDOUS MATERIALS COMMUNICATIONS, EMERGENCY RESPONSE INFORMATION, TRAINING REQUIREMENTS, AND SECURITY PLANS, Ariz. Admin. WebListing, classification and packing Mercury (UN 2809): Subsidiary risk 6.1 Transmitted by the expert from Germany Introduction 1. when all of the dangerous good safety marks can be seen through the overpack for each class of dangerous goods that is inside it, no additional labels or safety marks are required. WebMercury rarely occurs uncombined in nature, but can be found as droplets in cinnabar (mercury sulfide) ores. Subsection 2.2(4) and Parts 9 and 10 of the TDG Regulations authorize you to use the classification from the: Many substances in Schedule 1 are assigned one or more packing groups. 64-23-14 - 64-23-14 - Transportation of Radioactive Material. Transportation of Dangerous Goods (TDG) - 9 Classes, TDG "Special Case and Special Provision Exemptions. Guide for Preparing SHIPPING PAPERS - Transportation Note 3: The containers inside the package not required to bear TDG safety marks. How do I determine the identification number / UN Number? They are substances that are identified as Marine pollutants in the IMDG Code Index or substances that satisfy the GHS classification criteria for Hazardous to Aquatic Environment Acute 1, Chronic 1, or Chronic 2. 120.790 - 120.790 - Advance Notification of Shipment of Nuclear Waste, 180 Neb. (iii) the primary class, which may be shown as a number only or under the heading Class or Classe or following the word Class or Classe. if applicable, the technical name of the dangerous goods, the classification of the dangerous goods, and. Shipping Name and Description This column gives the shipping names for dangerous goods in alphabetical order within each primary class and within each packing group. The term "MARINE POLLUTANT" shall be put in the end of dangerous goods descriptions. /Producer(Sub Systems, Inc.)/CreationDate(D:20211224145622+05'00')/ModDate(D:20211224145622+05'00')/Creator(Sub Systems, Inc.) Please also see the following documents in this series: The consignor is responsible for determining the classification of dangerous goods. There are other considerations for some special dangerous goods, for which additional description words shall be added. b) The laboratory test results show the product falls into one class and one packing group. Mercury and its compounds. Who has responsibilities for dangerous goods safety marks? will be unavailable during this time. It is used for dangerous goods that do not have a specific entry by name in Schedule 1. (1) The total quantity of the material covered by one description must appear before or after, or both before and after, the description required and authorized by this subpart. (gasoline). Admin. to indicate that the flash point is a closed cup test value (e.g., 27 clesius degrees c.c.). Primary Class This column gives the primary class of the dangerous goods. But a sealed glass ampule holding mercurywhen the ampule is in the form of a long cylinder with lines marked on the side for measuring temperatureis a thermometer, a mercury article, and would be shipped as "UN 3506, MERCURY X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? Marine Pollutants: Mercury. Have the answers at your fingertips. However, if the product's name is not listed in Schedule 1 or 3, then the product must be tested at a laboratory. ), code or number for a particular hazard (e.g., 1- Explosive, 2 - Gases, 3 - Flammables), Provide quick identification of the dangerous goods in an emergency (e.g., release of dangerous goods during an incident), Communicate the nature and degree of the danger, Quickly determine if dangerous goods in a mixed load are incompatible, is determined to be a dangerous good under the TDG Regulations, and, displayed against a background of contrasting colour, made of durable, weather-resistant material that will resist coming detached or fade, Select the correct label(s) for each small means of containment (e.g., drum, package, overpack), Make sure that each small means of containment (e.g., package or container) of dangerous goods is properly labelled and marked, Select the correct placards and other safety marks for each large means of containment (e.g., tanker), Display the placards and other safety marks, or provide the appropriate placards to the carrier (when the means of containment or means of transport belongs to the carrier), Confirm that the safety marks are correct, Make sure the safety marks are displayed and remain displayed during transport, Replace safety marks when during transport they are stolen, lost, or defaced, Provide and display appropriate safety marks when the contents of the shipment change (e.g., new consignments are loaded on the means of transport), Remove or cover safety marks when the dangerous good is no longer present. 1. For example, UN3518 ADSORBED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. has three hazard classes assigned to it in Column 3 of Schedule 1. However, the safety mark requirements for large means of containment with a capacity of greater than 450 L but less than or equal to 3000 L (i.e., an intermediate bulk container) are: Placards are not required for overpacks as the definition and description for an overpack does not include large means of containment. Has a subsidiary classification of Class 1 (1.1,1.2, 1.3 above the exemption limits), Class 4.3, Class 6.1 (Packing Group I), Class 8 (applies only to UN numbers N2977 and UN2978). View Past Newsletter, http://www.unece.org/fileadmin/DAM/trans/danger/publi/adr/adr2011/English/Part3.pdf, http://www.phmsa.dot.gov/filename/Marine_Pollutant_Guidance.pdf, Biocides and Biocidal Product Regulations, Example: UN 1133 ADHESIVES containing flammable liquids; UN 1263, PAINT, Example: UN 1987 ALCOHOLS, N.O.S. Flammable Liquids 4. WebA subsidiary class placard is required to be displayed on a large means of containment for dangerous goods that requires an emergency response assistance plan (ERAP) if they The labels must be displayed on two opposite sides of the outer surface of a small means of containment. Read More: Marine Pollutants & Environmentally Hazardous Substances: Definition, Marking and Exceptions. Code 3701:1-50-23 - 3701:1-50-23 - Advance notification of shipment of irradiated reactor fuel and nuclear waste. Self-heating solid, corrosive, organic, n.o.s. Gross quantity of Class 1.4 (except Class 1.4S) is 1000 kg or less, Class1.1, 1.2, 1.3 or 1.5 explosives that are not subject to Special provision 85 or 86 in Schedule 2 of the TDG Regulations and the quantity is less than or equal to 10 kg, Class1.1, 1.2, 1.3 or 1.5 explosives that are subject to Special provision 85 or 86 in Schedule 2 of the TDG Regulations and the quantity is less than or equal to 1000 articles. Class 1 (explosives) materials; self-reactive substances; Division 5.2 materials; and entries that are not assigned a packing group (e.g., Class 7) are excepted from this requirement. Inhalation Hazard words on two opposite sides of the containment for dangerous goods: as listed in Special provision 23 in Schedule 2 of the TDG Regulations, classified in Class 6.1, Toxic substances because the dangerous good meets the inhalation toxicity criteria and Class 2.3, Toxic Gases, Elevated temperature sign (if applicable), Container certification or compliance marks as required by the standard that the container is compliant with, a placard and UN number may be displayed on two opposite sides of the intermediate bulk container, or, a label for each primary and subsidiary class as well as a UN number and a shipping name may be displayed on two opposite sides of the intermediate bulk container. Hazard class placards are required when the dangerous goods are: Hazard class placards are not required or are optional when only the following dangerous goods (one or more) are present in the shipment: Examples are available from the TDG Directorates FAQ on Part 4 under the question Can you explain the current placarding requirements?. The data below is an example showing UN1203, GASOLINE. Founded in 1961 and headquartered in Los Angeles, Mercury has assets in excess of $4 billion, employs 4,500 people and has more than 8,000 independent agents in 11 states (Arizona, California, (ii) The hazard class need not be included for the entry Combustible liquid, n.o.s.. Access to this website TN Rules and Regs. Where different hazardous materials in limited quantities are packed together in the same outer packaging, when a gross mass is indicated Column 4 of 173.27 Table 3, the net quantity of each hazardous material must be shown in addition to the gross mass of the completed package. Perchlorates. The packing group for a dangerous good is determined by using the laboratory test data and comparing it to the criteria in Part 2. Code. The required markings for overpacks include: Placards are not required for consolidation bins as the definition and description for a consolidation bin does not include large means of containment. WebClassification of dangerous goods is broken down into nine classes according to the type of danger materials or items present, click on a class to read more details; 1. There are 4 types of entries consisting of UN numbers and proper shipping names in the Dangerous Goods List. The labelling requirements for an overpack depend on whether the labels can be seen through the overpack. Note that the TDG Directorate has not examined or certified any of the laboratories. Mercury is a highly toxic metal and can cause skin irritation, skin rashes, allergic reactions. Note: The letters UN are not displayed, and the black numerals must not be less than 65 mm high. How do I determine the compatibility group? Which technical names shall be given in parenthesis for generic entries and N.O.S entries? The type of packages must be indicated by description of the package (for example, 12 drums). This requirement is outlined in Part 5 of the TDG Regulations. The following provisions also apply: (i) For empty uncleaned packaging, only the number and type of packaging must be shown; (ii) For chemical kits and first aid kits, the total net mass of hazardous materials must be shown. : AC413650000; AC413650025; AC413650050; AC413651000; AC413655000 CAS No 7783-35-9 Synonyms Mercuric sulfate NOTE: The size of the Inhalation hazard letters vary for different types of means of containment. UN 3506: Mercury contained in manufactured articles - Substance Once the material has been tested at a laboratory, the test results are compared to the classification criteria in Part 2. This sign must be displayed at or next to each entry way of the large means of containment (greater than 450 L) when the containment is fumigated with a dangerous good. If the product's name (e.g., chemical name) is listed in Schedule 1 or 3 then the primary hazard class is in Column 3 of Schedule 1 and in Column 2 of Schedule 3 for that shipping name. (d) Technical and chemical group names may be entered in parentheses between the proper shipping name and hazard class or following the basic description. If the product's name (e.g., chemical name) is listed in Schedule 1 or 3, the primary hazard class is listed in Column 3 of Schedule 1 as well as in Column 2 of Schedule 3 for that shipping name. SAFETY DATA SHEET - Fisher Sci Proper shipping name is the standard technical name to describethe hazard properties and the composition of dangerous goods. Browse our full range of workplace health and safety products and services. Browse our full range of workplace health and safety products and services. I, II or III) assigned to the substance or article. Hazard class (the primary class and possible subsidiary class/es), Packing group, compatibility group, or the infectious substance category for biohazardous substances, SHIPPING NAME (in Column 2 of Schedule 1): GASOLINE; MOTOR SPIRIT; or PETROL (when selecting the shipping name you can use one of the three listed names such as gasoline), Hazard Class (in Column 3 of Schedule 1): 3, Identification Number (in Column 1 of Schedule 1): UN1203, Packing Group (in Column 4 of Schedule 1): II, UN1096 SIGNALS, SMOKE which is not allowed to be transported on a ship. Safety data sheet SECTION 1: Identification of the (4) The packing group in Roman numerals, as designated for the hazardous material in Column (5) of the 172.101 table. Code DHS Sec. WebClassifying Substances That Are Included in More Than One Class or Packing Group The Primary class is shown first, with the subsidiary classes in brackets. Has a subsidiary classification of Class 1 (1.1,1.2, 1.3 above the exemption limits), Class 4.3, Class 6.1 (Packing Group I), Class 8 (applies only to UN numbers Miscellaneous Class 1 - Explosives 4 0 obj classified in Class 2.3, Toxic Gases hazard class, classified in Class 4.3, Water-reactive Substances hazard class and all packing groups, classified in Class 5.2, Organic Peroxides (Type B, liquid or solid, that require control temperature.)
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